| School | District | Grades | Population | Address - click for map | Phone |
| Athens Elementary School | Mercer County School District | K-8 | 491 | Po Box 568, Athens, WV 24712 | (304) 384–9229 |
| Bluefield High School | Mercer County School District | 9-12 | 696 | 535 W Cumberland Rd, Bluefield, WV 24701 | (304) 325–9116 |
| Bluewell Elementary School | Mercer County School District | K-5 | 170 | Rr 4 Box 480, Bluefield, WV 24701 | (304) 589–5057 |
| Bramwell Elementary School | Mercer County School District | K-6 | 85 | Po Box 358, Bramwell, WV 24715 | (304) 248–7150 |
| Brushfork Elementary School | Mercer County School District | K-5 | 242 | Rr 4 Box 93, Bluefield, WV 24701 | (304) 325–7066 |
| Ceres Elementary School | Mercer County School District | K-5 | 146 | Rr 2 Box 189, Bluefield, WV 24701 | (304) 325–6786 |
| Glenwood Elementary School | Mercer County School District | K-8 | 733 | Rr 1 Box 460, Princeton, WV 24740 | (304) 425–2445 |
| Lashmeet/matoaka Elementary School | Mercer County School District | K-8 | 439 | Po Box 408, Matoaka, WV 24736 | (304) 467–7477 |
| Melrose Elementary School | Mercer County School District | K-5 | 184 | Hc 71, Box 257, Princeton, WV 24740 | (304) 425–3757 |
| Memorial Elementary School | Mercer County School District | K-2 | 213 | 319 Memorial Ave, Bluefield, WV 24701 | (304) 327–8106 |
| Mercer Elementary School | Mercer County School District | 3-5 | 314 | 1200 Mercer St, Princeton, WV 24740 | (304) 425–3160 |
| Montcalm Elementary School | Mercer County School District | K-6 | 406 | Rr 2 Box 35, Rock, WV 24747 | (304) 589–7095 |
| Montcalm High School | Mercer County School District | 7-12 | 334 | Po Box 710, Montcalm, WV 24737 | (304) 589–3719 |
| Oakvale Elementary School | Mercer County School District | K-8 | 300 | P. O. Box 188, Oakvale, WV 24739 | (304) 898–3731 |
| Princeton High School | Mercer County School District | 9-12 | 1019 | 1321 Stafford Dr, Princeton, WV 24740 | (304) 425–8101 |
| Princeton Middle School | Mercer County School District | 6-8 | 624 | 300 N Johnston St, Princeton, WV 24740 | (304) 425–7517 |
| Spanishburg Elementary School | Mercer County School District | K-8 | 321 | Po Drawer 7, Spanishburg, WV 25922 | (304) 425–5854 |
| Sun Valley Elementary School | Mercer County School District | K-5 | 134 | Po Box 10, Lenore, WV 25676 | (304) 384–7441 |
| Whitethorn Elementary School | Mercer County School District | K-2 | 176 | 1919 Maryland Ave, Bluefield, WV 24701 | (304) 327–6217 |
| Bluefield Middle School | Mercer County School District | 6-8 | 574 | 2002 Stadium Dr, Bluefield, WV 24701 | (304) 325–2481 |
| Pikeview High School | Mercer County School District | 9-12 | 631 | 3566 Eads Mill Road, Princeton, WV 24740 | (304) 384–7586 |
| Alternative Learning Center | Mercer County School District | 7-9 | 0 | 105 Old Bluefield Road, Princeton, WV 24740 | (304) 487–1551 |
| Mercer County Early Learning Center | Mercer County School District | N/A | 174 | 821 Broadway Street, Princeton, WV 24740 | (304) 425–4251 |
| Bluefield Intermediate School | Mercer County School District | 3-5 | 399 | 1301 Southview Drive, Bluefield, WV 24701 | (304) 327–8339 |
| Princeton Primary School | Mercer County School District | K-2 | 581 | 219b Old Bluefield Road, Princeton, WV 24740 | (304) 487–2649 |
| Straley Elementary School | Mercer County School District | 3-5 | 181 | 810 Straley Ave, Princeton, WV 24740 | (304) 425–3173 |
| Mercer County Technical Education Center | Mercer County School District | 9-12 | 0 | 1397 Stafford Drive, Princeton, WV 24740 | (304) 425–9551 |
